Having spoken with Glenn about this in the past, primarily it was because getting good NOS 6SL7s (or 6SN7s) was expensive, and current production ones sound crap in comparison. Also, reliability wasn't consistent. As anyone who buys NOS tubes knows, you don't really know what you're getting until you plug it in and listen to it!
They might measure fine, but could still be noisy or develop faults, after even just light use when equipment is tested - and the bigger valves tend to be more 'temperamental', in that respect.
Current production ECC83s are relatively cheap, readily available, are generally reliable, and sound/perform consistently. I also believe that the circuit they use is easier and less costly to implement - all of which makes it a no-brainer decision for Glenn to use, instead of the larger octal valves, which when properly implemented, do sound better.
That said, the current range of Croft equipment still sounds superb, but in a different way... Most people just want to buy equipment fit for purpose, out of the box that sounds great, without faffing around modifying things, so the current stuff fits the bill. However, if you are prepared to go down the modification route, and seek out an old Charisma or Epoch, then the rewards (after spending a not inconsiderable sum on the necessary components) are significant.
Do remember also that Glenn will build virtually anything you want to your bespoke requirements, so if you wanted a 6SL7 or 6SN7-based preamp, designed from scratch, he'll do it for you and put it into a nice case. Obviously, however, that route will be more expensive than supplying him with a Charisma or Epoch to modify, as with the latter the core components and circuit are already in place.
Therefore, there's plenty of choice out there for anyone who wants to get a Croft preamp. Whatever you choose, you're guaranteed to end up with something rather special, which will provide significantly more 'SPPV value' than is available with designs other manufacturers are producing at many times the price!
Marco.