The way you propose to use the hole saw is feasible, but you could just cut a bit of MDF round to fit the existing holes and glue it in, then you could mark the centre and drill away with the hole saw.
The way you propose to use the hole saw is feasible, but you could just cut a bit of MDF round to fit the existing holes and glue it in, then you could mark the centre and drill away with the hole saw.