All very solid advice.It could be the speakers interaction with the room, my listening room makes everything a bit shouty and I have had to play with all sorts to ameliorate this effect which is a PITA. I'd wait till the other half is out and move the speakers and listening position around, also get some towels or blankets to break up reflection points as an earlier poster suggested. This will tell you how much the room can change the sound so you can judge this particular contribution to your problem, it could just be the 'smoking gun' and is free to do, if it works then proper room treatment is relatively affordable (if domestically acceptable). If the sound just remains shouty then I'm afraid you're going to have to think about trying a few different pairs of speakers IN YOUR ROOM.
Re. Valve amps the Audion might have something to do with your problem, but Zu speakers are designed with SETs in mind (unlike Tannoy DCs), and Paulf above enjoyed his Zu speakers with an even lower powered PX25 amp so I'd say unlikely to be a massive effect. Jerry's T-amp offer is sensible, a diffferent class of amp is needed to highlight any amp-speaker interactions should these be significant.
Re. Valves I am a bit OCD valve rolling and have rolled more 300b than I care to admit in SET, PSET, and PP amps. There are certainly differences but they are modest compared to speaker and room effects, they will flavour a well-functioning system, not cure a problem. If still keen you may be better off rolling the driver valves first as these often have a more pronounced effect, and are much cheaper and easier to sell on. If your valves are getting toward the end of their life then I'd expect a lifeless sound and weakening frequency extremes. That might sound shouty but lifeless doesn't seem like your system's problem?
Re. Servicing the amps, I'd get it done as a priority. I think I have read that (older) Audions run quite hot and towards the limit of component tolerances - maybe ne reason why they sound so good? A look over from someone like Graeme (Valvebloke on the Wam) or Mr Firebottle here could be prudent - there's a lot of expensive damage possible with a popped capacitor and your speakers (and house) deserve a bit of protection...boring but prudent. They will check over the valves at the same time so you know if there's a discernable problem there.