I don’t think it works like that.
If you are going to hear a difference between loudspeaker cables it will probably be because of changes to cable properties interacting with your amplifier and speakers.
What may work well with a particular combination may not sound so good when say the speakers or amplifier get changed. Some amplifiers tend to be less stable with high capacitance cables for example.
So, the idea that one can buy the best/most affordable cables and successfully swap kit around them is fallacious imo. Yer doing it wrong.
As for spending five hundred pounds on a mains lead
Single spur balanced Mains. Self built music server with 3 seperate linear PSU, Intel i5, 16 GB RAM no hard drive (various Linux OS). Benchmark Dac2 HGC, single ended XLR interconnects/Belkin cable. Exposure 21RC Pre, Super 18 Power (recap & modified). Modded World Audio HD83 HP amp. Hand built Monitors with external crossovers , Volt 250 bass & ABR, Scanspeak 13M8621 Mid & Scanspeak D2905/9300 Hi. HD595 & Beyer 880 (600 ohm) cans.
The whole problem with the world is that fools and fanatics are always so certain of themselves, and wiser people so full of doubts.
-Bertrand Russel
John.